What Are the Differences between Polyamide and Nylon?

2023.9.23

Polyamide and nylon are both common man-made synthetic materials. Although the chemical structures of both contain repeating units of imines and carboxylic acids, they still differ significantly in details.

The Definition, Material, Strength, Use, etc. of Polyamide and Nylon

The comparison table between polyamide and nylon is as follows:

PolyamideNylon
DefinitionThe raw materials of polyamide are mainly propylene glycol and imidazole acetimide, which are synthesized through dehydration and condensation reaction.The raw materials of nylon are mainly aliphatic dicarboxylic acids and Diamines, such as hexamethylene diamine and imidazole diamine.
MaterialLinear polymerSubpolymer
StrengthHigh strength but weak toughnessLow strength but good toughness
Main UsesClothing, medical materials, engineering plastics, etc.Fiber, can bags, fishing lines, etc.
Polymerization MethodPolyamide forms long-chain polymers by simply adding amide units for chain growth reaction.Nylon polymerizes through a combination of ring-opening polymerization and non-chain reactions.
Polymerization temperaturePolyamides are generally polymerized at relatively high temperatures (200-250°C).The polymerization temperature of nylon is relatively low, usually between 180-230°C.
Processing ProcessPolyamide is commonly processed using techniques such as rotation, extrusion, etc. The product can be obtained directly through ordinary forming processing.Nylon needs to be melt processed and formed through an extruder or infusion.
How To Identify Polyamide and Nylon?

Polyamide and nylon can be identified by the following methods:

Nylon will soften and deform when heated, and then begin to melt when heated further; polyamide will shake and deform after being heated, but will not melt.

– Nylon precipitate and acetic acid can form a soluble mixture, while polyamide and acetic acid are insoluble;

– Nylon and soda ash are easily soluble after soaking, while polyamide and soda ash are insoluble.

Nylon can be dissolved in strong alkaline solutions, acetone, benzene, etc.; polyamide can only be dissolved in strong acidic solutions such as dilute hydrogen chloride acid.

Pull the nylon to make a “zzzz” sound, and pull the polyamide to make a “cri cri” sound.

Nylon has a silky luster and a smooth surface; polyamide is viscous and soft to the touch.

Nylon is used as food by rats and small squirrels; polyamide is ignored by them.

Practical Examples of Polyamide and Nylon

PolyamideNylon
Clothingsweaters, T-shirts, underwear, hospital gownsStockings, flag Japan, sportswear
Medicalwaterproof wound causal dressing, gastric tubeTotal metabolism compound cannula
TransportationSmall Parts and AccessoriesVehicle ropes, tire reinforcement fibers
Householdtableware, slippers, plastic wrapLaundry bag, storage basket, cleaning brush
IndustrialBearings, gears, zippersFiber materials, canvas, steel rope
OtherBraces, prosthesesShoes, socks, sportswear, fishing line

Comparison of chemical properties of polyamide and nylon

Heat resistanceAcid resistanceAlkali resistanceSolvent resistance
PolyamideHighMediumMediumMedium
NylonMediumHighHighHigh

Comparison of physical properties of polyamide and nylon

DensityRefractive IndexFlammabilityMoisture Absorption
PolyamideMediumMediumHighHigh
NylonLowHighMediumLow

Price comparison of polyamide and nylon

Raw material costsProcessing costTotal cost
PolyamideMediumhighhigh
NylonlowMediumlow

Best Suppliers of Nylon and Polyamide

The prices of nylon and polyamide products from different suppliers will vary. Here is an overview of the price levels of several major suppliers: